{"abstract":[{"lang":"eng","text":" Polyacrylonitrile (PAN) nanofiber mats are typical precursors for carbon nanofibers. They can be fixed or even elongated during stabilization and subsequent carbonization to gain straight, mechanically robust carbon nanofibers. These processes necessitate additional equipment or are—if the nanofiber mats are just fixed at the edges—prone to resulting in the specimens breaking, due to an uneven force distribution. Hence, we showed in a previous study that electrospinning PAN on aluminum foils and stabilizing them fixed on these substrates, is a suitable solution to keep the desired morphology after stabilization and incipient carbonization. Here, we report on the influence of different metallic and semiconductor substrates on the physical and chemical properties of the nanofiber mats after stabilization and carbonization at temperatures up to 1200 °C. For stabilization on a metal substrate, an optimum stabilization temperature of slightly above 240 °C was found, approached with a heating rate of 0.25 K/min. Independent from the substrate material, SEM images revealed less defect fibers in the nanofiber mats stabilized and incipiently carbonized on a metal foil. Finally, high-temperature carbonization on different substrates is shown to allow for producing metal/carbon nano-composites.\r\n "}],"publication_identifier":{"eissn":["2311-5629"]},"type":"journal_article","main_file_link":[{"url":"https://doi.org/10.3390/c7010012","open_access":"1"}],"intvolume":" 7","language":[{"iso":"eng"}],"article_number":"12","alternative_id":["1625","2650"],"date_updated":"2023-10-04T13:12:28Z","author":[{"orcid_put_code_url":"https://api.orcid.org/v2.0/0000-0002-6841-8791/work/95037509","last_name":"Storck","full_name":"Storck, Jan Lukas","id":"221157","orcid":"0000-0002-6841-8791","first_name":"Jan Lukas"},{"id":"237316","first_name":"Bennet","last_name":"Brockhagen","full_name":"Brockhagen, Bennet"},{"full_name":"Grothe, Timo","last_name":"Grothe","orcid_put_code_url":"https://api.orcid.org/v2.0/0000-0002-9099-4277/work/94758815","first_name":"Timo","orcid":"0000-0002-9099-4277","id":"221330"},{"first_name":"Lilia","last_name":"Sabantina","full_name":"Sabantina, Lilia"},{"last_name":"Kaltschmidt","full_name":"Kaltschmidt, Bernhard","first_name":"Bernhard"},{"first_name":"Khorolsuren","id":"222971","full_name":"Tuvshinbayar, Khorolsuren","last_name":"Tuvshinbayar"},{"first_name":"Laura","full_name":"Braun, Laura","last_name":"Braun"},{"full_name":"Tanzli, Ewin","last_name":"Tanzli","first_name":"Ewin"},{"last_name":"Hütten","full_name":"Hütten, Andreas","first_name":"Andreas"},{"first_name":"Andrea","orcid":"0000-0003-0695-3905","id":"223776","full_name":"Ehrmann, Andrea","last_name":"Ehrmann","orcid_put_code_url":"https://api.orcid.org/v2.0/0000-0003-0695-3905/work/94758817"}],"issue":"1","publisher":"MDPI AG","oa":"1","quality_controlled":"1","volume":7,"doi":"10.3390/c7010012","keyword":["polyacrylonitrile (PAN)","nanofibers","electrospinning","aluminum","copper","tin","titanium","silicon wafer","steel","stabilization and carbonization"],"user_id":"245590","citation":{"bibtex":"@article{Storck_Brockhagen_Grothe_Sabantina_Kaltschmidt_Tuvshinbayar_Braun_Tanzli_Hütten_Ehrmann_2021, title={Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates}, volume={7}, DOI={10.3390/c7010012}, number={112}, journal={C}, publisher={MDPI AG}, author={Storck, Jan Lukas and Brockhagen, Bennet and Grothe, Timo and Sabantina, Lilia and Kaltschmidt, Bernhard and Tuvshinbayar, Khorolsuren and Braun, Laura and Tanzli, Ewin and Hütten, Andreas and Ehrmann, Andrea}, year={2021} }","ama":"Storck JL, Brockhagen B, Grothe T, et al. Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates. C. 2021;7(1). doi:10.3390/c7010012","mla":"Storck, Jan Lukas, et al. “Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates.” C, vol. 7, no. 1, 12, MDPI AG, 2021, doi:10.3390/c7010012.","ieee":"J. L. Storck et al., “Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates,” C, vol. 7, no. 1, 2021.","chicago":"Storck, Jan Lukas, Bennet Brockhagen, Timo Grothe, Lilia Sabantina, Bernhard Kaltschmidt, Khorolsuren Tuvshinbayar, Laura Braun, Ewin Tanzli, Andreas Hütten, and Andrea Ehrmann. “Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates.” C 7, no. 1 (2021). https://doi.org/10.3390/c7010012.","apa":"Storck, J. L., Brockhagen, B., Grothe, T., Sabantina, L., Kaltschmidt, B., Tuvshinbayar, K., … Ehrmann, A. (2021). Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates. C, 7(1). https://doi.org/10.3390/c7010012","short":"J.L. Storck, B. Brockhagen, T. Grothe, L. Sabantina, B. Kaltschmidt, K. Tuvshinbayar, L. Braun, E. Tanzli, A. Hütten, A. Ehrmann, C 7 (2021).","alphadin":"Storck, Jan Lukas ; Brockhagen, Bennet ; Grothe, Timo ; Sabantina, Lilia ; Kaltschmidt, Bernhard ; Tuvshinbayar, Khorolsuren ; Braun, Laura ; Tanzli, Ewin ; u. a.: Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates. In: C Bd. 7, MDPI AG (2021), Nr. 1"},"publication":"C","title":"Stabilization and Carbonization of PAN Nanofiber Mats Electrospun on Metal Substrates","date_created":"2021-05-31T18:59:11Z","status":"public","article_type":"original","_id":"1081","year":"2021","publication_status":"published","tmp":{"short":"CC BY (4.0)","image":"/images/cc_by.png","name":"Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)","legal_code_url":"https://creativecommons.org/licenses/by/4.0/legalcode"}}